Photo- and thermally induced coloration of a crystalline MOF accompanying electron transfer and long-lived charge separation in a stable host-guest system.
نویسندگان
چکیده
A new type of electron transfer (ET) system was built via the combination of a highly stable MOF host framework and methyl viologen guest molecule. The π-stacking arrangements adjust the distance between the D-A components, contributing to the formation of an ultra long-lived charge separated state in the photo/thermo dual stimuli-responsive complex.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 65 شماره
صفحات -
تاریخ انتشار 2012